23/02/2026
2/2 The study, published in Advanced Science, titled “High-Performance Quasi-Solid-State Calcium-Ion Batteries from Redox-Active Covalent Organic Framework Electrolytes”, introduces a novel CIB design based on redox covalent organic frameworks, that function as quasi-solid-state electrolytes (QSSEs). The integration of laboratory experiments with computational simulations demonstrated that not only these ordered nano-channels enhance ion transport capability (>0.53), but they also contribute to improving ionic conductivity (0.46 mS.cm–1) under ambient conditions, and structural stability of the battery during long-term operation.
Using this approach, the team successfully constructed a complete CIB cell. The prototype delivered a reversible specific capacity of 155.9 mAh.g⁻¹ at a current density of 0.15 A.g⁻¹. Even under a higher current density of 1 A g⁻¹, the battery maintained more than 74.6% of its original capacity after 1,000 charge-discharge cycles, indicating excellent durability and cycling performance.
According to the researchers, these results demonstrate that redox-active covalent organic framework electrolytes can significantly enhance the practicality of CIBs. The study highlights the strong potential of CIBs as an environmentally friendly alternative to lithium-based systems and represents an important step toward next-generation energy storage technologies suitable for clean energy infrastructures and future electric mobility.
Reference: “High-Performance Quasi-Solid-State Calcium-Ion Batteries from Redox-Active Covalent Organic Framework Electrolytes” by Zhuoyu Yin, Jixin Wu, Ye Tian, Yufei Yuan, Muhua Gu, Lei Cheng, Yanming Wang and Yoonseob Kim, 16 November 2025, Advanced Science.
DOI: 10.1002/advs.202512328
The project was conducted in collaboration with researchers at Shanghai Jiao Tong University.
Date: February 16-2026
Source: https://scitechdaily.com/breakthrough-calcium-ion-battery-could-challenge-lithium-for-clean-energy/
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