03/11/2022
We are talking about nitrogen today, but really about the entire nitrogen cycle. You should have learned all this in junior high so quiz your kids.
Nitrogen enters into water most commonly as either ammonia (NH4) or nitrate (NO3). Ammonia comes from biologic waste, decaying organic matter, and fish respiration. Ammonia is toxic to fish but in healthy environments is converted to other forms of nitrogen by nitrifying bacteria. The first step in the nitrogen cycle is ammonia being converted to nitrite (NO2) by bacteria like nitrosomonas. Nitrite is also toxic but luckily it’s converted by other nitrifying bacteria like nitrobacter to nitrate.
Nitrate is either then released back into the atmosphere or is used by phytoplankton and aquatic plants to grow. Other sources of nitrate outside of the nitrogen cycle are runoff, animal waste, and fertilizers. Nitrate is very safe for fish and is the end of the nitrogen cycle until biologic waste or decay starts it all over again as ammonia. The nitrogen cycle requires nitrifying bacteria, dissolved oxygen, and alkalinity. Without those present the nitrogen cycle is stuck at ammonia.
Ammonia is toxic to fish at low levels which lead to fish being more susceptible to bacterial infections and eventually death. Technically there are two types of ammonia but for these post we are not going to dive any further into that. For fish any ammonia level above .5mg/l is stressful, above 1.0 mg/l is dangerous, and 2.0 mg/l is deadly. If you have ever had fish die in a livewell ammonia was a likely part of the cause. Managing temperature, oxygen, and ammonia are the three components of good livewell fish care.
Nitrite can sometimes come from well water but is more commonly just from the nitrogen cycle. It’s toxic at any level above .1 mg/l so you want your waterbody to be at or near 0 all the time. Nitrate is rarely toxic so anything 0-5 mg/l is your goal but I wouldn’t stress until nitrate is higher then 50 mg/l.
With a healthy nitrogen cycle your pond will stay fertile but as soon as dissolved oxygen or alkalinity drop the nitrogen cycle grinds to a halt. I do recommend taking water samples on all three phases of nitrogen in your pond. During the summer I would do this both above and below the thermocline. This will give you an excellent understanding of where your plankton blooms are going as well as what risk you have for fish kills. At home aquarium kits can do these test for you or you can have local biologist or even well service companies run this analysis.