Life Cycle Associates, LLC

Life Cycle Associates, LLC Life Cycle Associates is a provider of environmental consulting services specializing in fuel systems and transportation. www.lifecycleassociates.com

We support renewable energy developers, fuel providers, government agencies, and environmental groups. Life Cycle Associates works with clients around the world to reduce harmful emissions and negative effects on the environment. Our qualifications are based on more than 60 years cumulative experience in fuels and renewable energies, fuel production processes, model development and process design,

GHG mitigation, delivery logistics, and fuel certification. Life Cycle Associates has completed numerous life cycle analysis studies, including those to establish fuel pathway carbon intensities (CI) to support the California Low Carbon Fuel Standard (LCFS). We helped biofuel developers assess their GHG footprint under government regulations including the EPA RFS2, California LCFS, Federal requirements on jet fuel, and the European Renewable Energy Directive.

05/11/2024

Bet it gets a good EER

Boris Grebenshchikov
06/15/2023

Boris Grebenshchikov

Join Life Cycle Associates and Christianson PLLP on June 7th at 9am PDT for an informative webinar on the Inflation Redu...
05/18/2023

Join Life Cycle Associates and Christianson PLLP on June 7th at 9am PDT for an informative webinar on the Inflation Reduction Act (IRA), Life Cycle Analysis (LCA), and GREET model fundamentals. Learn about farming CI compliance, maximizing incentives, and more. Register today!

The IRA webinar provides an overview of the Inflation Reduction Act (IRA), Life Cycle Analysis (LCA) and GREET model fundamentals, farming CI compliance, and procedures for applying for the tax credit.

The Biofuels Digest recognized Stefan Unnasch as one of the outstanding leaders in driving the growth of the bioeconomy ...
05/15/2023

The Biofuels Digest recognized Stefan Unnasch as one of the outstanding leaders in driving the growth of the bioeconomy in its Bioeconomy 500 for 2023 list. Read the full article below👇

The Biofuels Digest recognized Stefan Unnasch as outstanding leader in driving the growth of the bioeconomy in its Bioeconomy 500 for 2023 list.

Renewable Fuel Standard (RFS) saved more than 1.2 billion metric tons of greenhouse gas emissions. Read about our most r...
03/13/2023

Renewable Fuel Standard (RFS) saved more than 1.2 billion metric tons of greenhouse gas emissions. Read about our most recent study by clicking on the article below👇👇👇

Life Cycle Associates study confirms the RFS has resulted in aggregate GHG reductions from the use of biofuels that exceed the EPA’s original projections.

Stefan Unnasch will participate in the panel “Even Better than Expected” at the National Ethanol Conference at 11 am on ...
02/21/2023

Stefan Unnasch will participate in the panel “Even Better than Expected” at the National Ethanol Conference at 11 am on Thursday, March 2. We hope to see you there.

Stefan Unnasch will present at the National Ethanol Conference on findings from the updated GHG Emissions Reductions due to the RFS2 study.

Stefan Unnasch, Managing Director of Life Cycle Associates, will be speaking at the Sustainable Aviation Futures North A...
12/06/2022

Stefan Unnasch, Managing Director of Life Cycle Associates, will be speaking at the Sustainable Aviation Futures North America 2022 congress. The congress provides insights on North America’s sustainable aviation landscape. Click the link below to find out more👇

Stefan Unnasch speaks at the Sustainable Aviation Futures North America 2022 congress covering insights on North America’s sustainable aviation landscape.

Hydrogen planes will need an EER under the LCFS.  What about SPK with its higher energy density?
06/02/2022

Hydrogen planes will need an EER under the LCFS. What about SPK with its higher energy density?

Best Use of Biomass Enabling Hydrogen Flight.Sustainable aviation fuel (SAF) is a biofuel that has properties similar to...
06/01/2022

Best Use of Biomass Enabling Hydrogen Flight.

Sustainable aviation fuel (SAF) is a biofuel that has properties similar to conventional jet fuel with reduced life cycle greenhouse gas (GHG) emissions, or carbon intensity (CI). SAF’s low CI provides a solution to reducing aviation GHGs that make up 9 to 12% of U.S. transportation GHG emissions. SAF created from renewable biomass and waste resources has the potential to deliver the performance of petroleum-based jet fuel but with a fraction of its carbon footprint.

Biomass is a renewable organic resource that includes agriculture crop residues, forest residues, crops grown for energy use, organic municipal solid waste, and animal wastes. Growing biomass removes CO2 from the atmosphere which means the net carbon emissions are low, especially when coupled with carbon capture and sequestration (CCS). Gasification and pyrolysis are routes to the conversion of biomass to SAF. Gasification process converts organic or fossil-based carbonaceous materials to carbon monoxide and other gases. A water-gas shift reaction is utilized to react the CO with water to form CO2 and hydrogen. Absorbers or special membranes separate the hydrogen from the gas stream. Recycled carbon can react with renewable hydrogen to increase the production of renewable fuel.

Producing SAF from renewable and waste resources creates economic opportunities in farming communities, improves the environment, and boosts aircraft performance. SAF burns cleaner in aircraft engines as it contains fewer aromatic components, reducing the impact of contrails on climate change. As a result, there are lower local emissions around airports. Furthermore, the production of biofuels contributes to the domestic economy by creating jobs, forging new economic benefits.

Prepared by Stefan Unnasch and Kathleen Dailey, Life Cycle Associates, LLC - Date: May 31, 2022

Please let us know if you have a question or would like further information about Life Cycle Associates’ work and services. Contact details 884 Portola Road, Suite A11 Portola Valley, CA 94028 +1 650 461 9048 +1 484 313 9504 [email protected] Your Name (required) Your Email (require...

Hydrogen Won’t Fly Today. Aviation is responsible for 2.1% of all human-induced CO2 emissions (ATAG, 2022). Modern plane...
05/31/2022

Hydrogen Won’t Fly Today.

Aviation is responsible for 2.1% of all human-induced CO2 emissions (ATAG, 2022). Modern planes use kerosene as fuel, which releases CO2 into the atmosphere. A solution to the CO2 emitted is hydrogen fuel, which does not produce emissions. is a sustainable fuel and is now gaining attention as a possible aviation fuel alternative. Planes using hydrogen would only emit water and still function as well as traditional planes.

Commercial hydrogen aircraft is far from being a reality - reports estimate hydrogen powered aviation will begin entering the market by 2035 (O'Callaghan, 2020). Developments in liquid hydrogen storage could lead to medium-range flight up to 4,400 mi by 2040, leaving long-range flights to traditional aviation fuel. The refueling infrastructure does not exist and hydrogen is more expensive and difficult to store onboard than kerosene-based fuel. Bringing hydrogen fuel to the market has significant challenges. If overcome, the aviation industry could be much greener, contributing to a decarbonized world. Of course, the legacy fleet of 25,000 jets, which is expected to grow to over 35,000 (Cooper, 2017) by 2035 will continue to operate on kerosene. Even if a goal (AirBus, 2022) of hydrogen flight by 2035 is achieved, most flights will still require kerosene through the middle of the century.

Although hydrogen is promising, it won’t be able to deliver net-zero carbon emissions on its own. Biomass-derived sustainable aviation fuel (SAF) is developing beyond waste oils and fats. Synthetic paraffinic kerosene (SPK) is a bio-derived fuel that provides the means to deliver renewable hydrogen as aviation fuel due to its higher energy density and chemical composition.

While liquid hydrogen provides the opportunity for zero emission flight, challenges with cryogenic storage on the plane and fuel infrastructure mean that this option is decades away.

Hydrogen-powered flight is a potential way forward. Aesthetically, hydrogen planes would be similar to traditional planes. Smaller planes would use hydrogen-powered fuel cells that provide electric propulsion to turn propellers, while larger planes could burn hydrogen to power jet engines (O'Callaghan, 2020). Hydrogen planes would require developments in propulsion, on-board storage, airport logistics, as well as redesign of the entire plane which would replace wing storage of fuel with cryogenic tanks. Planes would need to be refueled where new ways of transporting hydrogen to airports is required.

Furthermore, the energy density of liquid hydrogen is approximately a quarter of jet fuel - for the same amount of energy it needs a storage tank four times the size (Henderson, 2021). While integration is a challenge, standards, codes, and regulations need to be prepared. Currently, liquid hydrogen is three times as expensive as conventional jet fuel and is likely to remain that way for the next few decades - limiting liquid hydrogen’s role in greening aviation.

The choice of aircraft architecture is dominated by the location of the hydrogen storage. The diameter of liquid hydrogen tanks affects the gravimetric efficiency and internal volume, where a solution is an increased fuselage volume (FlyZero, 2022). The FlyZero project led by Aerospace Technology Institute came up with a concept for a liquid hydrogen-powered midsize aircraft that would be able to fly 279 passengers non-stop from London to San Francisco, or from London to Auckland, New Zealand with one stop for refueling (Holt, 2021). The aircraft has a 54-meter wingspan and two turbofan engines and would offer the same speed and comfort as today’s aircraft with zero emissions. Cryogenic fuel tanks would be included in the rear fuselage, storing hydrogen at -250 degrees Celsius. Two smaller tanks along the forward fuselage would keep the plane balanced as fuel is used.

Priority technology challenges for hydrogen powered aircraft that need to be addressed before achieving certification and entering service include the following:

- Liquid hydrogen behavior and materials compatibility data
- Liquid hydrogen storage
- Cryogenic fluid pumps
- Hydrogen combustion systems
- Aircraft integration of cryogenic hydrogen fuel systems

While pursuing research of hydrogen aircraft is promising. The challenge in achieving net-zero carbon emissions by 2050 is that hydrogen will not be able to deliver this on its own. Low carbon impact available in limited quantities from waste oils and plants like carinata, algae, and camelina are just under development. Parallel investment in biomass-based SAF is required to achieve carbon neutral flying goals. As each option has advantages, it is too early to choose one over the other as the solution to decarbonize aviation.

Hydrogen has the highest energy density of any fuel, shown in Table 1, with more than double the energy density of conventional jet fuel - an airplane could achieve long range flight on pure hydrogen if it could be stored. SPK has a 1% higher energy density than conventional jet because of its chemical composition with more hydrogen per carbon atom. The improved energy density of SPK results in a reduction of fuel weight. For example, a 2,000-mile trip would require 364 kg less fuel to go the same distance based on the conventional jet fuel use and energy for a typical cargo airplane shown in the table. Assuming a comparable energy use for flight, the weight of liquid hydrogen would be less than that of jet fuel but additional weight for the storage system would result in added weight and developing and certifying designs to accommodate liquid hydrogen will take over a decade.

SPK provides a practical means to deliver renewable hydrogen as an airplane fuel. It has an improved energy density over conventional jet fuel and is available from low GHG emitting sources. The carbon in biomass is saturated with hydrogen to make a pure straight chain hydrocarbon to achieve a higher energy density than conventional jet fuel.

Table 1. SPK provides improved energy density compared to conventional jet fuel. The weight reduction results in 643 MJ of energy savings over a 2,000-mile flight. That’s 14.6 kg of fuel savings that is not burned or 364 kg of additional cargo that the plane can carry (Source: GREET)

References
AirBus. (2022). ZEROe Towards the world’s first zero-emission commercial aircraft: https://www.airbus.com/en/innovation/zero-emission/hydrogen/zeroe
ATAG. (2022). Air Transport Actin Group. Retrieved from Facts & Figures: www.atag.org/facts-figures.html
Argonne National Laboratory. (2021). GREET : The Greenhouse Gases, Regulated Emissions, and Energy Use in Technologies Model
FlyZero. (2022). Zero-Carbon Emission Aircraft Concepts. Aerospace Technology Institute.
Henderson, C. (2021, April 7). The hydrogen revolution in the skies. Retrieved from Airbus: https://www.bbc.com/future/article/20210401-the-worlds-first-commercial-hydrogen-plane
Holt, K. (2021, December 6). Tech Crunch. Retrieved from Designers hope hydrogen-powered plane will fly halfway around the world without refueling: https://techcrunch.com/2021/12/06/designers-hope-hydrogen-powered-plane-will-fly-halfway-around-the-world-without-refueling/
O'Callaghan, J. (2020, July 8). Horizon - The EU Research & Innovation Magazine. Retrieved from Quiet and green: Why hydrogen planes could be the future of aviation: https://ec.europa.eu/research-and-innovation/en/horizon-magazine/quiet-and-green-why-hydrogen-planes-could-be-future-aviation
Cooper, T. et al. (2017). Global Fleet & MRO Market Forecast Summary. 2017-2027 Oliver Wyman report.


New Hydrogen Station in Sunnyvale
02/12/2021

New Hydrogen Station in Sunnyvale

Sunnyvale Hydrogen Station Opens The Sunnyvale True Zero station, located in Silicon Valley, was developed by FirstElement Fuel. It will be open 24 hours a day and is located at 1296 Sunnyvale Saratoga Road, Sunnyvale, CA 94087. The price of hydrogen is $13.08 per kilogram. The Sunnyvale hydrogen st...

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